The 1977 and 1978 episodes were originally broadcasted as segments on the package show Scooby's All-Star Laff-A-Lympics and Scooby's All-Stars. The 1980 episodes featured Captain Caveman and the Teen Angels in their own half-hour timeslot.
The Scarifying Seaweed Secret
The Dummy
Cavey and the Volcanic Villain
Prehistoric Panic
Cavey and the Baffling Buffalo Man
Dragonhead
Cavey and the Murky Mississippi Mystery
Old Cavey in New York
Cavey and the Albino Rhino
Kentucky Cavey
Cavey Goes to College
The Haunting of Hog's Hollow
The Legend of Devil's Run
The Mystery of the Meandering Mummy
The Old Caveman and the Sea
Lights, Camera... Cavey!